Хахель, Олег АльбіновичРомашко, Таміла Петрівна2019-10-062019-10-062019-06https://dspace.pdau.edu.ua/handle/123456789/5963The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is sug- gested. A validity of such approach was verified by the example of studying of extrathermodynamic compensa- tions. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of pyrene excimers.extrathermodynamicsArticlehttps://doi.org/10.1016/j.heliyon.2019.e01839