Ромашко, Таміла Петрівна2019-02-252019-02-252007-06O. A. Khakhel’, T. P. Romashko, Y. E. Sakhno, One More Type of Extra Thermodynamic Relationship. J. Phys. Chem. B, 111 (2007) 7331−7335.https://dspace.pdau.edu.ua/handle/123456789/3443A new type of extrathermodynamic relationship is presented: ¢H ) Ti[¢S + R ¢(ln ¿)] + â, where ¿ is the phase volume and â is a constant. This type of relationship holds for a series of systems in the case where ä¢(ln ¿) is changeable. The relation between this type of correlation and linear free-energy relationships is shown. An example of the specified correlation for energy parameters of excimers forming in different dipyrenylalkanes is demonstrated.enextrathermodynamicsArticle10.1021/jp0725275