Synchronous fluorescence spectroscopy for investigating aggregation phenomena in polymer matrix

Короткова, Ірина Валентинівна; Korotkova, I. V.; Ромашко, Таміла Петрівна; Romashko, T. P.; Хахель, Олег Альбінович; Khakhel, O. A.

Публікація:
Synchronous fluorescence spectroscopy for investigating aggregation phenomena in polymer matrix

dc.contributor.author	Короткова, Ірина Валентинівна
dc.contributor.author	Korotkova, I. V.
dc.contributor.author	Ромашко, Таміла Петрівна
dc.contributor.author	Romashko, T. P.
dc.contributor.author	Хахель, Олег Альбінович
dc.contributor.author	Khakhel, O. A.
dc.date.issued	2025
dc.description	Korotkova I., Romashko T., Khakhel O. Synchronous fluorescence spectroscopy for investigating aggregation phenomena in polymer matrix. International Journal of Chemical Studies. 2025. Vol. 13 (3). P. 11-20. DOI: 10.22271/chemi.2025.v13.i3a.12533
dc.description.abstract	Organic photoluminescent materials, such as fluorescent polymers and small fluorescent molecules, are widely used in optoelectronics, sensing, bioimaging, and related fields. However, their practical application is often limited by aggregation-induced fluorescence quenching in concentrated solutions or solid-state environments. To enable rational use of such materials, spectroscopic tools capable of detecting spectral manifestations of aggregation are essential. In this study, we proposed the use of synchronous fluorescence spectroscopy (SFS) to investigate aggregation-related spectral features in various polymer matrices containing phenyl-based chromophores and some aromatic compounds, including 9,10-diphenylanthracene, pyrene, anthracene, and naphthalene. SFS exhibited high sensitivity in identifying aggregate-related spectral features, including excimer-like emission and bathochromic shifts, both in solid matrices and liquid media. The results demonstrate that SFS is an effective diagnostic tool for probing aggregation behavior and optimizing the photophysical properties of polymeric luminescent materials.
dc.identifier.uri	https://dspace.pdau.edu.ua/handle/123456789/21411
dc.language.iso	en
dc.subject	spectral manifestations of aggregation
dc.subject	dimer
dc.subject	excimer
dc.subject	synchronous fluorescence spectroscopy
dc.title	Synchronous fluorescence spectroscopy for investigating aggregation phenomena in polymer matrix
dc.type	Article
dspace.entity.type	Publication