The origin of extrathermodynamic compensations
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Date
2019-06
Authors
Хахель, Олег Альбінович
Ромашко, Таміла Петрівна
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Abstract
Description
The way of analysis of thermodynamic systems, which takes into consideration systems’ phase volumes, is sug-
gested. A validity of such approach was verified by the example of studying of extrathermodynamic compensa-
tions. Several types of exact linear extrathermodynamic compensations as well as their peculiar type, which
peculiarity is indefinable compensation temperature, are established. The criteria that specify these types are
stated. These results are illustrated by the identified exact extrathermodynamic compensations in formation of
pyrene excimers.
Keywords
extrathermodynamics