One More Type of Extrathermodynamic Relationship
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Date
2007-06
Authors
Ромашко, Таміла Петрівна
Journal Title
Journal ISSN
Volume Title
Publisher
ACS
Abstract
A new type of extrathermodynamic relationship is presented: ¢H ) Ti[¢S + R ¢(ln ¿)] + â, where ¿ is the phase volume and â is a constant. This type of relationship holds for a series of systems in the case where
ä¢(ln ¿) is changeable. The relation between this type of correlation and linear free-energy relationships is
shown. An example of the specified correlation for energy parameters of excimers forming in different dipyrenylalkanes is demonstrated.
Description
Keywords
extrathermodynamics
Citation
O. A. Khakhel’, T. P. Romashko, Y. E. Sakhno, One More Type of Extra Thermodynamic Relationship. J. Phys. Chem. B, 111 (2007) 7331−7335.